Methanol steam reforming msr reaction has been seen as a very attractive and promising process for hydrogen production and, according to the scientific literature on the argument, it can be described by the following chemical reactions. Copper supported on znoal 2 o 3 oxides is the most commonly used catalyst for methanol steam reforming due to its high activity at low temperatures and high selectivity to h 2. Methanol steam reforming behavior of copper impregnated over ceo 2 zro 2 derived from a surfactant assisted coprecipitation route. A methanol reformer is a device used in chemical engineering, especially in the area of fuel cell technology, which can produce pure hydrogen gas and carbon dioxide by reacting a. Progress in methanol steam reforming modelling via membrane. Methanol steam reforming for hydrogen generation via conventional. Pdf progress in methanol steam reforming modelling via. He later obtained his masters degree in chemical engineering, also from washington state university, in 2005. Technical and economic assessment of methanol production from. The use of membrane reactors makes it possible to lower the temperature of this process by 100c, increase the selectivity of the process, and practically eliminate the effect of catalysts carbonization. Herein, znoal 2o 3 and alkalidoped znoal 2o 3 catalysts were prepared by coprecipitation method and incipientwetness impregnation method, respectively, and characterized by means of xrd, bet and ftir. Nov 27, 2012 a nonsyngas direct steam reforming route is investigated for the conversion of methanol to hydrogen and carbon dioxide over a cuzngaox catalyst at 150200 c.
In contrast, catalyst poisoning and coking have been observed in methanol decomposition and methanol steam reforming reactions. Gas chromatography of reformate via autothermal reforming, 4. Carbon monoxide is known to be very poisonous to pt catalyst used in pemfcs. An empiric correlation derived on the base of previous experimental studies is suggested to bring the simulation results closer to the actual findings.
Methanol reformers are large largest reformer has 960 tubes two to three times the size of an ammonia reformer many reformers in the range 600900 tubes why is this. Methanol steam reforming for hydrogen production chemical. Unlike the steam reforming reaction, methanol synthesis creates heat and this type of heat of reaction is called exothermic. From a technical point of view methanol is the ideal fuel, as it can easily be converted into hydrogen at reasonable temperatures technology. International journal of hydrogen energy 2015, 40 33, 1046310479. Us7592292b2 catalyst for use in reforming methanol with. Autothermal reforming of coalderived methanol mixing effects in steam reforming have already been shown to be of great significance to. In the field of hydrogen generation from methanol steam reforming reaction, a consistent literature is. Furthermore, it shows a relatively high hc ratio and low reforming temperature, ranging from 200 to 300 c.
In this study, au catalysts supported on modified montmorillonite were prepared and their catalytic activity for. Pdf methanol steam reforming for hydrogen generation via. Methanol steam reforming for hydrogen generation via. Methanol production based on steam reforming of natural gas 5. A method of manufacturing a copperbased catalyst having high activity and superior heat resistance and a catalyst used for steam reforming of methanol has al alloy particles each having an oxide surface layer containing fine copper oxide particles. His masters thesis was titled fuel processing catalysis for microchannel applications. Steam reforming of natural gas at petroleum refining facilities is the predominant means of producing hydrogen in the chemical process industries cpi. Steam reforming is a highly endothermic process which is carried out by passing a mixture of steam and natural gas over a catalyst 16.
Pdf hydrogen production from steammethanol reforming. Catalytic steam reforming of methanol to produce hydrogen on supported metal catalysts 151 increase the overall efficiency of ceo2 for different applications. Steam methane reforming is the most common and economical way to make hydrogen. Naphtha steam reforming catalyst reduction with methanol process information disclaimer information contained in this publication or as otherwise supplied to users is believed to be accurate and correct at time of going to press, and is given in good faith, but it is for the user to satisfy itself of the. In methanol synthesis involving modern promoted cuznoal2 o3 catalysts neither poisoning nor coking is normally a significant source of deactivation. Gas chromatography of reformate via steam reforming, 3. Methanol production ferdowsi university of mashhad. Cual spinel oxide as an efficient catalyst for methanol. Proven autothermal reforming technology for modern large. Pdf methanol steam reforming for hydrogen production. Novel reformer technologies such as sorbent enhanced reforming, ion transport membranes, and plasma reformers are discussed. Lowtemperature hydrogen production from methanol steam.
A methanol reformer is a device used in chemical engineering, especially in the area of fuel cell technology, which can produce pure hydrogen gas and carbon dioxide by reacting a methanol and water steam mixture. A tubular packedbed reactor performing the methanol steam reforming msr process was modeled by adopting computational fluid dynamics cfd software. Mann department of chemistry and chemical engineering, royal military college of canada, kingston, ont. Methanol synthesis also requires the use of a catalyst and the reaction takes place at a feed temperature that allows the best conditions for optimum production. Steam reforming for hydrogen production reforming reactions the principal process for converting hydrocarbons into hydrogen is steam reforming 6,7 which involves the following reactions. Hydrogen production by methanol steam reforming on. The capacity of methanol plant has increased by 300 mtpd with addition of co2 in synthesis gas mixture as excess h2 is available for the methanol reaction. Methanol steam reforming over nial and ni m al layered double. This technology is attractive at capacities greater than 25003000 mtpd methanol and the main licensor is haldor topsose 5.
Steam reforming or steam methane reforming is a method for producing syngas hydrogen and carbon monoxide by reaction of hydrocarbons with water. Microwave heating of endothermic catalytic reactions. Technical and economic assessment of methanol production. Steam methane reforming a majority of the methanol plants operating today are based on steam reforming of natural gas, as shown in figure 3. The omission of prereduction not only avoids the copper sintering prior to the catalytic reaction, but also slows down the copper. Methanol steam reforming is a promising process for the generation of hydrogen. From a technological perspective a solid oxide electrolysis cell soec was adapted to the process schemes. High purity hydrogen from coalderived methanol has been produced and testing with a nexa. The reason is, partly to improve composition of reactants for methanol synthesis and to enable a power peak.
Micromachined methanol steam reforming system as a hydrogen. Methanol steam reforming is one of the approaches on the rise due to its high energy density and relatively low reforming temperature 200300 c. Methanol steam reforming and selective co methanation. From a technical point of view methanol is the ideal fuel, as it can easily be converted into hydrogen at reasonable temperatures steam carbon molar ratio 41 reforming temperature and pressure 42 methanol production process steps 43 steam methane reformer chemistry 44 steam methane reforming scheme 44 partial oxidation pox chemistry 45 combined reforming chemistry 46 autothermal reforming atr chemistry 47 methanol synthesis reaction chemistry 49 methanol synthesis. Steam reforming of methanol for fuel cell grade hydrogen. Org 500 mtpd of co2 is recovered from the flue gas using mhis proprietary ks1 solvent and injected in synthesis loop for boosting methanol production. Areas where hydrogen is heavily consumed include ammonia production, the cryogenics industry and methanol production table 11. Different reaction paths of methanol steam reforming are simulated and analysed.
Sep 11, 2014 cual spinel oxide, which contains a small portion of the cuo phase, has been successfully used in methanol steam reforming msr without prereduction. Modeling methanol steam reforming for internal combustion. Hydrogen production from methanol steam reforming over. Methanol steam reforming is studied using the thermodynamic equilibrium assumption and the gibbs free energy minimization method. Dingler satish nirula walter sedriks february 1983. Catalytic steam reforming of methanol to produce hydrogen on. Kinetics, catalysis and mechanism of methane steam reforming. Advances in methanol production and utilization, with.
In order to achieve near equilibrium conversion, steam reforming in conventional technology is conducted on a supported nickel catalyst in a multitubular reactor operated at a temperature of 850c, a pressure. Naphtha steam reforming catalyst reduction with methanol. Simulations of hydrogen production by methanol steam reforming. Ethanol contains higher number of hydrogen per molecule as compared to water, methanol and methane. In the reforming reaction, natural gas is mixed with steam, heated to over 1,500 degrees fahrenheit, and reacted with nickel catalyst to produce hydrogen h. During steam reforming of ethanol, catalyst plays a major role in the productivity and selectivity of generated gas.
King haldor topsoe as copenhagen, denmark with global demand for methanol continuing its steady rise, improvements in methanol. Hydrogen production by steam reforming chemical engineering. Ceo2 has been widely used in purifying vehicle exhausts and became the most important rare oxides for nox reduction. Modeling methanol steam reforming for internal combustion engine leonid tartakovsky, vladimir baibikov, mark veinblat faculty of mechanical engineering, technion israel institute of technology, haifa 32000, israel. These include steam methane reforming smr, partial oxidation pox, autothermal reforming atr, methanol reforming, ammonia cracking and catalytic cracking of methane.
A nonsyngas direct steam reforming route is investigated for the conversion of methanol to hydrogen and carbon dioxide over a cuzngaox. Apr 16, 2004 in an endothermic reaction, such as methanol. All reforming is done in this reformer there is no secondary therefore choose the cheapest design and easiest to scale up therefore use top fired why. Pdf hydrogen has attracted growing attention for various uses, and, particularly, for polymer electrolyte membrane fuel cells pemfcs supply find, read. The main purpose of this technology is hydrogen production. Interplay of support chemistry and reaction conditions on. The intermetallic compound znpd and its role in methanol. Nonsyngas direct steam reforming of methanol to hydrogen and. Methanol steam reforming is studied using the thermodynamic equilibrium assumption and the gibbs free. Methane steam reforming reaction behaviour in a packed bed. Jul 30, 20 methanol reformers are large largest reformer has 960 tubes two to three times the size of an ammonia reformer many reformers in the range 600900 tubes why is this. Methane steam reforming reaction behaviour in a packed.
Heat transfer from the reactor wall normally supplies the required energy in such processes. During steam reforming of ethanol, catalyst plays a major role in. Progress in methanol steam reforming modelling via. Catalytic steam reforming of methanol to produce hydrogen. Proven autothermal reforming technology for modern largescale methanol plants per juul dahl thomas s. Methanol steam reforming for fuel cell applications. This paper will deal with large scale hydrogen production in stationary plants using steam reforming. Methanol steam reforming over nadoped znoal2o3 catalysts. The superheated steam is mixed with natural gas in the reforming reaction, producing hydrogen gas and carbon monoxide. A nonsyngas direct steam reforming route is investigated for the conversion of methanol to hydrogen and carbon dioxide over a cuzngaox catalyst. Cual spinel oxide, which contains a small portion of the cuo phase, has been successfully used in methanol steam reforming msr without prereduction. Costs of synthesis gases and methanol part i i by janet e.
The reaction of methanol steam reforming was studied in a carbon membrane reactor, comprising the previously studied cms membranes and cuoznoal2o3. Methanol steam reforming reaction for hydrogen generation. Methanol steam reforming msr is a promising process to produce hydrogen suitable for polymer electrolyte membrane fuel cells, but the development of catalysts with high activity and selectivity at low temperature is highly needed. In addition to this, the methanol steam reforming produces a relatively small amount of carbon monoxide at low temperature. Methanol steam reforming in membrane reactors springerlink. Meanwhile, there is a comprehensive literature about inorganic membrane reactors utilization for hydrogen generation via methanol steam reforming reaction. Hydrogen production by the catalytic steam reforming of methanol. Methanol steam reforming for hydrogen generation via conventional and membrane reactors. Deactivation of copper metal catalysts for methanol. Review of small stationary reformers for hydrogen production. Micromachined methanol steam reforming system as a. Fuel cell testing with reformate via steam reforming, 5.
414 529 1102 310 747 90 1080 1472 431 1494 605 1385 613 1492 59 891 1239 1229 1079 841 622 104 1179 384 1332 94 1506 1291 587 580 196 313 1142 375 531 1578 124 301 363 623 1463 1034 20 1116 338 760